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Affiliation |
Faculty of Science Depertment of Chemistry |
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Title |
Assistant Professor |
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External Link |
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NAKAYA Manabu
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Research Interests 【 display / non-display 】
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金属錯体
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固体物性
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機能性超分子
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機能性材料
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生物無機化学
Research Areas 【 display / non-display 】
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Nanotechnology/Materials / Inorganic/coordination chemistry
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Nanotechnology/Materials / Functional solid state chemistry
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Nanotechnology/Materials / Bio chemistry
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Natural Science / Magnetism, superconductivity and strongly correlated systems
From School 【 display / non-display 】
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Kumamoto University Faculty of Science Graduated
2009.04 - 2013.03
Country：Japan
From Graduate School 【 display / non-display 】
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Kumamoto University Graduate School, Division of Science and Technology Doctor's Course Completed
- 2018.03
Country：Japan
Employment Record in Research 【 display / non-display 】
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Josai University Faculty of Science Depertment of Chemistry Assistant Professor
2020.04
External Career 【 display / non-display 】
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Josai University Faculty of Sciences Department of Chemistry Assistant Professor
2020.04
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東京大学大学院 理学系研究科 日本学術振興会特別研究員
2018.04 - 2020.03
Country：Japan
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The University of Tokyo
2018.04 - 2020.03
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Japan Society for the Promotion of Science
2018.04 - 2020.03
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Japan Society for the Promotion of Science
2015.04 - 2018.03
Professional Memberships 【 display / non-display 】
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錯体化学会
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日本化学会 生体機能関連部会
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錯体化学 若手の会
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日本化学会
Papers 【 display / non-display 】
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pH-driven optical changes of platinum(II) complexes having carboxy-appended salophen ligands Reviewed
Shun Fujii, Hajime Yagi, Tomohiro Kawaguchi, Mitsuru Ishikawa, Naoki Izumiyama, Manabu Nakaya
Dalton Transactions 52 ( 29 ) 10206 - 10212 2023
Authorship：Corresponding author Publishing type：Research paper (scientific journal) Publisher：Royal Society of Chemistry (RSC)
The present carboxy-appended platinum(ii) complexes exhibit UV-vis and luminescence spectra changes by the protonation/deprotonation trrigered by the addition of acid and base.
DOI： 10.1039/d3dt00956d
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Light-induced excited spin state trapping in iron(iii) complexes Reviewed
Manabu Nakaya, Ryo Ohtani, Leonard F. Lindoy, Shinya Hayami
Inorganic Chemistry Frontiers 8 ( 2 ) 484 - 498 2021
Authorship：Lead author Publishing type：Research paper (scientific journal) Publisher：Royal Society of Chemistry (RSC)
<p>This review discusses the correlation of the local and whole molecular structure of iron(<sc>iii</sc>) complexes with the magnetic properties including the light-induced excited spin-state trapping (LIESST) effect.</p>
DOI： 10.1039/d0qi01188f
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Metal-Dependent DNA Base Pairing of 5-Carboxyuracil with Itself and All Four Canonical Nucleobases Reviewed
Yusuke Takezawa, Akira Suzuki, Manabu Nakaya, Kotaro Nishiyama, Mitsuhiko Shionoya
Journal of the American Chemical Society 142 ( 52 ) 21640 - 21644 2020.12
Language：English Publishing type：Research paper (scientific journal) Publisher：American Chemical Society ({ACS})
DOI： 10.1021/jacs.0c11437
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Guest Modulated Spin States of Metal Complex Assemblies Reviewed
Manabu Nakaya, Ryo Ohtani, Shinya Hayami
European Journal of Inorganic Chemistry 2020 ( 39 ) 3709 - 3719 2020.10
Authorship：Lead author
© 2020 Wiley-VCH GmbH Recently, “host–guest chemistry” aspects of material science have received much attention, particularly in relation to moderating the functions of materials. In particular, magnetic properties involving the “magnetic ordering” and “spin crossover” of host–guest metal complex systems have been actively investigated in terms of their host–guest chemistry. That is, systems in which the magnetic properties are sensitive to perturbation by the uptake of guests (which thus act as chemical stimuli). Such guests (solvents, gases and organic molecules) very often influence the structures of both discrete metallosupramolecular assemblies as well as those of coordination polymers/metal-organic frameworks (CPs/MOFs), providing a means for fine-tuning their magnetic behavior, including the switching of their spin states. In this minireview, we report recent progress in the development and investigation of magnetic materials of both the CP and MOF categories as well as of discrete complexes whose properties are modulated by guests.
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CO2-Induced Spin-State Switching at Room Temperature in a Monomeric Cobalt(II) Complex with the Porous Nature Reviewed International journal
Manabu Nakaya, Wataru Kosaka, Hitoshi Miyasaka, Yuki Komatsumaru, Shogo Kawaguchi, Kunihisa Sugimoto, Yingjie Zhang, Masaaki Nakamura, Leonard F. Lindoy, Shinya Hayami
Angewandte Chemie - International Edition 59 ( 26 ) 10658 - 10655 2020.03
Authorship：Lead author Language：English Publishing type：Research paper (scientific journal)
© 2020 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim CO2-responsive spin-state conversion between high-spin (HS) and low-spin (LS) states at room temperature was achieved in a monomeric cobalt(II) complex. A neutral cobalt(II) complex, [CoII(COO-terpy)2]⋅4 H2O (1⋅4 H2O), stably formed cavities generated via π–π stacking motifs and hydrogen bond networks, resulting in the accommodation of four water molecules. Crystalline 1⋅4 H2O transformed to solvent-free 1 without loss of porosity by heating to 420 K. Compound 1 exhibited a selective CO2 adsorption via a gate-open type of the structural modification. Furthermore, the HS/LS transition temperature (T1/2) was able to be tuned by the CO2 pressure over a wide temperature range. Unlike 1 exhibits the HS state at 290 K, the CO2-accomodated form 1⊃CO2 (P (Formula presented.) =110 kPa) was stabilized in the LS state at 290 K, probably caused by a chemical pressure effect by CO2 accommodation, which provides reversible spin-state conversion by introducing/evacuating CO2 gas into/from 1.
Misc 【 display / non-display 】
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結晶状態における核酸塩基対形成を利用した金属錯体分子の集積化 Invited
仲谷 学、大谷 亮
Dynamical Ordering & Integrated Functions Newsletter 2017.04
Language：Japanese Publishing type：Article, review, commentary, editorial, etc. (scientific journal)
Awards 【 display / non-display 】
Scientific Research Funds Acquisition Results 【 display / non-display 】
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Construction of metal complex assemblies using DNA-template and the application for functional films
Grant number：22K14695 2022.04 - 2024.03
Japan Society for the Promotion of Science Grants-in-Aid for Scientific Research Grant-in-Aid for Early-Career Scientists Grant-in-Aid for Early-Career Scientists
Grant amount：\4680000 （ Direct Cost: \3600000 、 Indirect Cost：\1080000 ）
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Assembly control and development of functions of external stimuli responsive coordination polymers using anisotropic hydrogen bonds by nucleobases
Grant number：18J02137 2018.04 - 2021.03
Japan Society for the Promotion of Science Grants-in-Aid for Scientific Research Grant-in-Aid for JSPS Fellows Grant-in-Aid for JSPS Fellows
Grant amount：\3640000 （ Direct Cost: \2800000 、 Indirect Cost：\840000 ）
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Development of external stimuli responsible metal complex assembly based on nucleobase pair formation
Grant number：15J11333 2015.04 - 2018.03
Japan Society for the Promotion of Science Grants-in-Aid for Scientific Research Grant-in-Aid for JSPS Fellows Grant-in-Aid for JSPS Fellows
Grant amount：\2800000 （ Direct Cost: \2800000 ）
Other External Funds 【 display / non-display 】
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外部刺激に応答した集積構造ダイナミクスに基づく分子性スピン変換材料の開発
2023.07 - 2024.03
池谷科学技術振興財団 単年度研究助成
Authorship：principal_investigator
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塩基対形成・開裂を利用した金属錯体の異方集積化と機能開拓
2022.06 - 2023.03
日本私立学校振興・共済事業団 若手・女性研究者奨励金
仲谷 学
Authorship：principal_investigator
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水素結合型金属錯体における異方的なネットワーク構築と機能開拓
2021.06 - 2022.05
徳山科学技術振興財団 スタートアップ助成
Authorship：principal_investigator
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水素結合型金属錯体集積体の合成および機能評価
2020.09 - 2022.03
城西大学 学長所管研究奨励金
Authorship：principal_investigator